资源类型

期刊论文 126

年份

2023 19

2022 12

2021 11

2020 13

2019 4

2018 6

2017 13

2016 3

2015 9

2014 3

2013 7

2012 4

2011 1

2010 2

2009 7

2008 4

2007 3

2005 1

2004 1

2000 1

展开 ︾

关键词

增材制造 5

加压浸出 2

激光选区熔化 2

电子束 2

选区激光熔化 2

选择性激光熔化 2

CCS 1

CO2分离 1

HEMTs）；栅槽；数字湿法腐蚀；选择性湿法腐蚀 1

ITO 1

五模材料 1

人造金红石 1

介观尺度模型 1

介观模型 1

偶氮苯 1

元素硫 1

分子开关 1

加压酸浸 1

动力学 1

展开 ︾

检索范围：

排序： 展示方式：

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 749-758 doi: 10.1007/s11705-022-2261-0

摘要： Since lithium iron phosphate cathode material does not contain high-value metals other than lithium, it is therefore necessary to strike a balance between recovery efficiency and economic benefits in the recycling of waste lithium iron phosphate cathode materials. Here, we describe a selective recovery process that can achieve economically efficient recovery and an acceptable lithium leaching yield. Adjusting the acid concentration and amount of oxidant enables selective recovery of lithium ions. Iron is retained in the leaching residue as iron phosphate, which is easy to recycle. The effects of factors such as acid concentration, acid dosage, amount of oxidant, and reaction temperature on the leaching of lithium and iron are comprehensively explored, and the mechanism of selective leaching is clarified. This process greatly reduces the cost of processing equipment and chemicals. This increases the potential industrial use of this process and enables the green and efficient recycling of waste lithium iron phosphate cathode materials in the future.

关键词： lithium iron phosphate powder     stoichiometric number     selective leaching     lithium recovery    

HTML PDF 收藏

Electrochemistry during efficient copper recovery from complex electronic waste using ammonia based solutions

Zhi Sun, Hongbin Cao, Prakash Venkatesan, Wei Jin, Yanping Xiao, Jilt Sietsma, Yongxiang Yang

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 308-316 doi: 10.1007/s11705-016-1587-x

摘要： Leaching selectivity during metal recovery from complex electronic waste using a hydrochemical process is always one of the generic issues. It was recently improved by using ammonia-based leaching process, specifically for electronic waste enriched with copper. This research proposes electrodeposition as the subsequent approach to effectively recover copper from the solutions after selective leaching of the electronic waste and focuses on recognising the electrochemical features of copper recovery. The electrochemical reactions were investigated by considering the effects of copper concentration, scan rate and ammonium salts. The diffusion coefficient, charge transfer coefficient and heterogeneous reaction constant of the electrodeposition process were evaluated in accordance with different solution conditions. The results have shown that electrochemical recovery of copper from ammonia-based solution under the conditions of selective electronic waste treatment is charge transfer controlled and provide bases to correlate the kinetic parameters with further optimisation of the selective recovery of metals from electronic waste.

关键词： copper recovery     electronic waste     end-of-life products     selective leaching     electrodeposition    

HTML PDF 收藏

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要： Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词： municipal solid waste incineration (MSWI) fly ash     blast furnace slag     leaching behavior     Cr     Pb    

HTML PDF 收藏

Assessment of leaching behavior and human bioaccessibility of rare earth elements in typical hospital

Chunfeng Wang, Guanfei Chen, Yanchen Zhu, Dan Yao, Wanfeng Wang, Lianjun Wang

《环境科学与工程前沿（英文）》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0946-2

摘要： Leaching behavior and gastrointestinal bioaccessibility of rare earth elements (REEs) from hospital waste incineration (HWI) fly and bottom ash samples collected from Beijing and Nanjing Cities were assessed. In the same ash sample, the leaching concentrations of individual REEs determined by the Toxicity Characteristic Leaching Procedure (TCLP) were higher than those detected by the European standard protocol (EN-type test), thereby suggesting that the low pH value of leaching solution was an important factor influencing the leachability of REE. The REE bioaccessibility results, which were evaluated using the physiologically based extraction test (PBET), indicated that REEs were highly absorbed during gastric phase by dissolution; and subsequently precipitated and/or re-adsorbed in small intestinal phase. The relative amounts of the total REEs extracted by the TCLP method, EN-type test and PBET test were compared. In addition to the pH value of extraction solutions, the chelating role of REEs with organic ligands used in the PBET method was also an important parameter affecting REE adsorption in human body. Additionally, this study showed that REEs were extracted by these methods as concomitants of heavy metals and anions (NO , F , SO , and Cl ) from HWI ash, which probably caused the remarkably complex toxicity on human body by the exposure pathway.

关键词： Assessment     Rare earth elements     Leaching behavior     Bioaccessibility     Hospital waste    

HTML PDF 收藏

Investigation of Cu leaching from municipal solid waste incinerator bottom ash with a comprehensive approach

Jun YAO, Wenbing LI, Fangfang XIA, Jing WANG, Chengran FANG, Dongsheng SHEN

《能源前沿（英文）》 2011年 第5卷 第3期   页码 340-348 doi: 10.1007/s11708-010-0131-9

摘要： Municipal solid waste incinerator (MSWI) bottom ash is often reused as a secondary construction material. This study used a comprehensive approach to characterize the leaching behavior of copper (Cu) from the MSWI bottom ash. The batch titration procedure was used to determine the acid neutralizing capacity and Cu leaching as a function of pH. The sequential extraction procedure (SEP) was adopted to analyze the speciation of Cu in the MSWI bottom ash. The metal speciation equilibrium model for surface and ground water (Visual MINTEQ) was used to evaluate the equilibrium of the leachates with the relative minerals, and to determine the speciation of the aqueous Cu in the leachates. Based on the multi-analysis of the results, Cu would be significantly released from the MSWI bottom ash when it is acidic. The Cu leaching pattern was not only affected by dissolved organic carbon, it was also limited by its speciation in the MSWI bottom ash. Furthermore, almost 100% of the aqueous Cu in the leachate was bound to organic matter in basic and neutral conditions, but mostly existed as Cu in an acidic condition. These findings provide an important insight into predicting the leaching behavior of Cu from the MSWI bottom ash, as well as its impact on the environment.

关键词： MSWI bottom ash     Cu leaching     batch titration procedure     SEP    

HTML PDF 收藏

The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 317-327 doi: 10.1007/s11705-017-1622-6

摘要： This study reports on the impact of the curing conditions on the mechanical properties and leaching of inorganic polymer (IP) mortars made from a water quenched fayalitic slag. Three similar IP mortars were produced by mixing together slag, aggregate and activating solution, and cured in three different environments for 28 d: a) at 20 °C and relative humidity (RH) ~ 50% (T20RH50), b) at 20 °C and RH≥90% (T20RH90) and c) at 60 °C and RH ~ 20% (T60RH20). Compressive strength (EN 196-1) varied between 19 MPa (T20RH50) and 31 MPa (T20RH90). This was found to be attributed to the cracks formed upon curing. Geochemical modelling and two leaching tests were performed, the EA NEN 7375 tank test, and the BS EN 12457-1 single batch test. Results show that Cu, Ni, Pb, Zn and As leaching occurred even at high pH, which varied between 10 and 11 in the tank test’s leachates and between 12 and 12.5 in the single batch’s leachates. Leaching values obtained were below the requirements for non-shaped materials of Flemish legislation for As, Cu and Ni in the single batch test.

关键词： inorganic polymer     geochemical leaching modelling     heavy metals     recycling     non-ferrous fayalitic slag     curing    

HTML PDF 收藏

Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 562-570 doi: 10.1007/s11705-020-1946-5

摘要： A two-stage leaching process, namely, high-pressure acid leaching-atmospheric acid leaching, was used to treat laterite ores under mild conditions. The leaching ratio of Ni was low because of adsorption and incomplete leaching. In this work, surfactants were used as additives to boost the leaching ratio of Ni. The effect of surfactant type (cationic, anionic, and nonionic surfactants) on the leaching ratio of Ni was investigated. Leaching results showed that stearyl trimethyl ammonium chloride (STAC) apparently increased the leaching ratios of valuable metals. The variation in the physicochemical properties of the lixiviant and the residue improved the leaching ratio of Ni in the presence of STAC. Kinetics analysis indicated that the leaching process was controlled by chemical reaction.

关键词： laterite ore     Ni     surfactant     acid leaching    

HTML PDF 收藏

Oxidative leaching kinetics of molybdenum-uranium ore in H

T. A. Lasheen, M. E. El-Ahmady, H. B. Hassib, A. S. Helal

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 95-102 doi: 10.1007/s11705-013-1317-6

摘要： The processing of molybdenum-uranium ore in a sulfuric acid solution using hydrogen peroxide as an oxidant has been investigated. The leaching temperature, hydrogen peroxide concentration, sulfuric acid concentration, leaching time, particle size, liquid-to-solid ratio and agitation speed all have significant effects on the process. The optimum process operating parameters were: temperature: 95°C; H O concentration: 0.5 M; sulfuric acid concentration: 2.5 M; time: 2 h; particle size: 74 μm, liquid-to-solid ratio: 14 ∶ 1 and agitation speed: 600 rpm. Under these experimental conditions, the extraction efficiency of molybdenum was about 98.4%, and the uranium extraction efficiency was about 98.7%. The leaching kinetics of molybdenum showed that the reaction rate of the leaching process is controlled by the chemical reaction at the particle surface. The leaching process follows the kinetic model 1 ? (1? ) = with an apparent activation energy of 40.40 kJ/mole. The temperature, concentrations of H O and H SO and the mesh size are the main factors that influence the leaching rate. The reaction order in H SO was 1.0012 and in H O it was 1.2544.

关键词： leaching of molybdenum     leaching of uranium     kinetics    

HTML PDF 收藏

铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

《中国工程科学》 2009年 第11卷 第5期   页码 18-22

摘要：

绍了新开发出来的一种具有较好工业应用前景的铜阳极泥预处理新工艺，小型及半工业试验结果表明，铜阳极泥直接加压酸浸，可以充分利用生阳极泥中水溶性铜离子的催化氧化作用，提高反应速度；在连续浸出过程中Ag，Se，Te走向与间断浸出过程差别明显，使浸出效果优于间断加压浸出预处理工艺，有利于提高有价元素的综合回收。

关键词： 铜阳极泥     综合利用     加压酸浸     连续浸出    

HTML PDF 收藏

Leaching of aluminum from coal spoil by mechanothermal activation

Xiaoxue SUN,Yuzhu SUN,Jianguo YU

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 216-223 doi: 10.1007/s11705-015-1518-2

摘要： The process of activating coal spoil (CS) in order to recover aluminum as a high value product was investigated. The CS was first characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and thermogravimetric analysis-differential scanning calorimetry (TGA-DSC) in order to determine the chemical and mineral compositions of the CS. Then a mechanothermal activation method was adopted to increase the aluminum activity in the coal spoil. Over 95% of the aluminum in the CS could be extracted using this activation method. The mechanothermal activation process promoted the destruction of kaolinite structures and hindered the formation of amorphous -Al O . This resulted in a high aluminum leaching activity in the mechanothermally activated CS.

关键词： coal spoil     mechanothermal compound activation     leaching    

HTML PDF 收藏

Leaching toxicity characteristics of municipal solid waste incineration bottom ash

Khamphe PHOUNGTHONG,Yi XIA,Hua ZHANG,Liming SHAO,Pinjing HE

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 399-411 doi: 10.1007/s11783-015-0819-5

摘要： The continuously increasing production of municipal solid waste incineration bottom ash (MSWIBA) has promoted its utilization as construction material and raised environmental concern. The physico-chemical properties and leaching behavior of MSWIBA were studied, and ecotoxicological testing using a luminescent bacterium bioassay was performed to assess the ecological pollution risks associated with its leached constituents. The MSWIBA was leached by two types of leachants, H SO /HNO and HAc solution, at different liquid to solid ratios and contact times. The concentrations of heavy metals and anions in the leachates were analyzed. Multivariate statistical analyses, including principle component analysis, Pearson's correlation analysis and hierarchical cluster analysis, were used to evaluate the contributions of the constituents to the toxicity ( ) of the MSWIBA leachate. The statistical analyses of the ecotoxicological results showed that the Ba, Cr, Cu, Pb, F and total organic carbon (TOC) concentrations were closely correlated with the value, and these substances were the main contributors to the ecotoxicity of the MSWIBA leachate. In addition, the cluster of these variables indicated similar leaching behaviors. Overall, the research demonstrated that the ecotoxicological risks resulting from MSWIBA leaching could be assessed before its utilization, which provides crucial information for the adaptation of MSWIBA as alternative materials.

关键词： Municipal solid waste incineration     bottom ash     alternative material     leaching tests     toxicity     Vibrio qinghaiensis (Q67)    

HTML PDF 收藏

矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

《中国工程科学》 2000年 第2卷 第6期   页码 49-51

摘要：

介绍了高铅铜型难处理金矿矿浆电解浸出机理的研究结果。金精矿在矿浆电解时，铅的浸出可通过化学溶解、化学氧化、阳极氧化三种途径；铅浸出的主要途径是靠化学溶解，矿粒与阳极接触而被氧化对浸出的贡献不大。

关键词： 矿浆电解     浸出     机理    

HTML PDF 收藏

Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 142-153 doi: 10.1007/s11705-015-1516-4

摘要： Recent advances with Pd containing catalysts for the selective hydrogenation of acetylene are described. The overview classifies enhancement of catalytic properties for monometallic and bimetallic Pd catalysts. Activity/selectivity of Pd catalysts can be modified by controlling particle shape/morphology or immobilisation on a support which interacts strongly with Pd particles. In both cases enhanced ethylene selectivity is generally associated with modifying ethylene adsorption strength and/or changes to hydride formation. Inorganic and organic selectivity modifiers (i.e., species adsorbed onto Pd particle surface) have also been shown to enhance ethylene selectivity. Inorganic modifiers such as TiO change Pd ensemble size and modify ethylene adsorption strength whereas organic modifiers such as diphenylsulfide are thought to create a surface template effect which favours acetylene adsorption with respect to ethylene. A number of metals and synthetic approaches have been explored to prepare Pd bimetallic catalysts. Examples where enhanced selectivity is observed are generally associated with decreased Pd ensemble size and/or hindering of the ease with which an unselective hydride phase is formed for Pd. A final class of bimetallic catalysts are discussed where Pd is not thought to be the primary reaction site but merely acts as a site where hydrogen dissociation and spillover occurs onto a second metal (Cu or Au) where the reaction takes place more selectively.

关键词： acetylene     ethylene     selective hydrogenation     palladium     bimetallic    

HTML PDF 收藏

Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 745-754 doi: 10.1007/s11705-021-2038-x

摘要： Selective swelling of block copolymers of polysulfone-b-poly(ethylene glycol) is an emerging strategy to prepare new types of polysulfone ultrafiltration membranes. Herein, we prepared nanoporous polysulfone-b-poly(ethylene glycol) ultrafiltration membranes by selective swelling and further promoted their porosity and ultrafiltration performances by using CaCO3 nanoparticles as the sacrificial nanofillers. Different contents of CaCO3 nanoparticles were doped into the solution of polysulfone-b-poly(ethylene glycol), and thus obtained suspensions were used to prepare both self-supported and bi-layered composite structures. Selective swelling was performed on the obtained block copolymer structures in the solvent pair of ethanol/acetone, producing nanoporous membranes with poly(ethylene glycol) lined along pore walls. The CaCO3 nanoparticles dispersed in polysulfone-b-poly(ethylene glycol) were subsequently etched away by hydrochloric acid and the spaces initially occupied by CaCO3 provided extra pores to the block copolymer layers. The porosity of the membranes was increased with increasing CaCO3 content up to 41%, but further increase in the CaCO3 content led to partial collapse of the membrane. The sacrificial CaCO3 particles provided extra pores and enhanced the connectivity between adjacent pores. Consequently, the membranes prepared under optimized conditions exhibited up to 80% increase in water permeance with slight decrease in rejection compared to neat membranes without the use of sacrificial CaCO3 particles.

关键词： block copolymers     selective swelling     ultrafiltration     CaCO3 nanoparticles     sacrificial nanofillers    

HTML PDF 收藏

高铁闪锌矿精矿加压浸出半工业试验研究

王吉坤,周廷熙,吴锦梅

《中国工程科学》 2005年 第7卷 第1期   页码 60-64

摘要：

高铁闪锌矿经二段加压浸出，锌浸出率97.09%，铁浸出率15.2%，元素硫产率93%，浸出液残酸3.95g/L，经简单中和、净化，生产合格硫酸锌新液供应锌电积。为了研究比较，闪锌矿经一段加压浸出，锌的浸出率98.09%，铁浸出率37.88%，元素硫产率96%，浸出液残酸高（46.4g/L），可并入现有传统湿法炼锌工艺流程处理。

关键词： 高铁闪锌矿     加压浸出     半工业试验     元素硫    

HTML PDF 收藏

标题 作者 时间 类型 操作

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

期刊论文

Electrochemistry during efficient copper recovery from complex electronic waste using ammonia based solutions

Zhi Sun, Hongbin Cao, Prakash Venkatesan, Wei Jin, Yanping Xiao, Jilt Sietsma, Yongxiang Yang

期刊论文

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

期刊论文

Assessment of leaching behavior and human bioaccessibility of rare earth elements in typical hospital

Chunfeng Wang, Guanfei Chen, Yanchen Zhu, Dan Yao, Wanfeng Wang, Lianjun Wang

期刊论文

Investigation of Cu leaching from municipal solid waste incinerator bottom ash with a comprehensive approach

Jun YAO, Wenbing LI, Fangfang XIA, Jing WANG, Chengran FANG, Dongsheng SHEN

期刊论文

The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

期刊论文

Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

期刊论文

Oxidative leaching kinetics of molybdenum-uranium ore in H

T. A. Lasheen, M. E. El-Ahmady, H. B. Hassib, A. S. Helal

期刊论文

铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

期刊论文

Leaching of aluminum from coal spoil by mechanothermal activation

Xiaoxue SUN,Yuzhu SUN,Jianguo YU

期刊论文

Leaching toxicity characteristics of municipal solid waste incineration bottom ash

Khamphe PHOUNGTHONG,Yi XIA,Hua ZHANG,Liming SHAO,Pinjing HE

期刊论文

矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

期刊论文

Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

期刊论文

Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and

期刊论文

高铁闪锌矿精矿加压浸出半工业试验研究

王吉坤,周廷熙,吴锦梅

期刊论文